{"id":1116,"date":"2011-11-14T17:01:52","date_gmt":"2011-11-14T08:01:52","guid":{"rendered":"http:\/\/www.qcri.or.jp\/lab\/?page_id=1116"},"modified":"2011-12-01T12:57:45","modified_gmt":"2011-12-01T03:57:45","slug":"re_power","status":"publish","type":"page","link":"https:\/\/qcri.or.jp\/lab\/ja\/research_ja\/re_power","title":{"rendered":"\u5316\u5b66\u306b\u304a\u3051\u308b\u529b\u306e\u6982\u5ff5"},"content":{"rendered":"<div id=\"paragraph2\">\n<div>\u3000\u4e2d\u8fbb\u306f\u3001\u300e\u9759\u96fb\u529b\u7406\u8ad6\u300f\u3068\u547c\u3070\u308c\u308b\u3001\u5206\u5b50\u306e\u69cb\u9020\u3084\u5316\u5b66\u53cd\u5fdc\u306b\u304a\u3051\u308b\u529b\u306e\u6982\u5ff5\u3092\u63d0\u6848\u3057\u3066\u3044\u307e\u3059\u3002 \u30d5\u30a7\u30eb\u30de\u30f3\u2015\u30d5\u30a1\u30a4\u30f3\u30de\u30f3\u306e\u9759\u96fb\u7406\u8ad6<\/div>\n<div><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter\" src=\"https:\/\/qcri.or.jp\/lab\/imgs\/HFtheorem.gif\" alt=\"H-F theorem\" width=\"388\" height=\"71\" \/><\/div>\n<div>\u306b\u3088\u308c\u3070\u3001\u539f\u5b50\u6838<em>A<\/em>\u306b\u50cd\u304f\u529b\u306f\u3001 \u5206\u5b50\u5185\u306e\u4ed6\u306e\u539f\u5b50\u6838<em>B<\/em>\u304b\u3089\u306e\u9759\u96fb\u53cd\u767a\u529b\u3068\u3001\u8ca0\u306b\u5e2f\u96fb\u3057\u305f\u96fb\u5b50\u96f2\u304c\u3001\u539f\u5b50\u6838<em>A<\/em>\u306b\u53ca\u307c\u3059\u5f15\u529b\u306e \u30d9\u30af\u30c8\u30eb\u548c\u306b\u306a\u308a\u307e\u3059\u3002<\/div>\n<div>?<\/div>\n<div>\u3000\u9759\u96fb\u529b\u7406\u8ad6\u306b\u3088\u308c\u3070\u3001\u5206\u5b50\u69cb\u9020\u3084\u5316\u5b66\u53cd\u5fdc\u306e\u7d4c\u8def\u306f\u3001\u5206\u5b50\u3092\u69cb\u6210\u3059\u308b\u539f\u5b50\u6838\u306b\u50cd\u304f\u3053\u308c\u3089\u306e\u529b\u306e\u30d9\u30af\u30c8\u30eb\u548c \u3092\u8003\u616e\u3059\u308b\u3053\u3068\u3067\u76f4\u89b3\u7684\u306b\u4e88\u6e2c\u3067\u304d\u307e\u3059\u3002 \u7279\u306b\u5206\u5b50\u306e\u69cb\u9020\u3092\u4e88\u6e2c\u3059\u308b\u65b9\u6cd5\u3068\u3057\u3066\u3001\u9759\u96fb\u529b\u7406\u8ad6\u306f\u3001Walsh\u5247\u3084VSEPR\u6cd5\u3088\u308a\u6b63\u78ba\u304b\u3064\u7c21\u5358\u3067\u3001 \u975e\u5e38\u306b\u512a\u308c\u3066\u3044\u307e\u3059\u3002<\/div>\n<div>?<\/div>\n<div>\u3000\u4e0b\u56f3\u306f\u3001\u4e09\u89d2\u5f62(\u6b6a\u66f2\u5f62)\u3067\u5b89\u5b9a\u306a\u5206\u5b50X\u304c\u52b1\u8d77\u72b6\u614b\u3067\u76f4\u7dda\u5f62\u306b\u306a\u308b\u4f8b\u3092\u3001 \u9759\u96fb\u529b\u7406\u8ad6\u306e\u8003\u3048\u3067\u8aac\u660e\u3057\u3066\u3044\u307e\u3059\u3002<\/div>\n<div>?<\/div>\n<div><img decoding=\"async\" src=\"https:\/\/qcri.or.jp\/lab\/imgs\/ESF1.png\" alt=\"\" \/><\/div>\n<div>?<\/div>\n<hr \/>\n<div id=\"reference\"><strong>References<\/strong><\/div>\n<ul>\n<li>Electrostatic Force Theory for a Molecule and Interacting Molecules I. Concept and Illustrative Applications, H. Nakatsuji, J. Am. Chem. Soc., 95(2), 345 (1973).<\/li>\n<li>Force Models for Molecular Geometry, H. Nakatsuji and T. Koga, in The Force Concept in Chemistry, B. M. Deb, Ed. (Van Nostrand Reinhold, New York,1981), Chap.3, pp. 137-217.<\/li>\n<li>Common Natures of the Electron Cloud of the System Undergoing Change in Nuclear Configuration, H. Nakatsuji, J. Am. Chem. Soc., 96(1), 24 (1974).<\/li>\n<li>Force in SCF Theories, H. Nakatsuji, K. Kanda, and T. Yonezawa, Chem. Phys. Lett., 75(2), 340 (1980).<\/li>\n<li>Force in SCF Theories. Second Derivative of Potential Energy, H. Nakatsuji, K. Kanda, and T. Yonezawa, J. Chem. Phys., 77, 1961 (1982).<\/li>\n<\/ul>\n<\/div>\n","protected":false},"excerpt":{"rendered":"<p>\u3000\u4e2d\u8fbb\u306f\u3001\u300e\u9759\u96fb\u529b\u7406\u8ad6\u300f\u3068\u547c\u3070\u308c\u308b\u3001\u5206\u5b50\u306e\u69cb\u9020\u3084\u5316\u5b66\u53cd\u5fdc\u306b\u304a\u3051\u308b\u529b\u306e\u6982\u5ff5\u3092\u63d0\u6848\u3057 &hellip; <a href=\"https:\/\/qcri.or.jp\/lab\/ja\/research_ja\/re_power\">\u7d9a\u304d\u3092\u8aad\u3080 <span class=\"meta-nav\">&rarr;<\/span><\/a><\/p>\n","protected":false},"author":2,"featured_media":0,"parent":1598,"menu_order":0,"comment_status":"closed","ping_status":"open","template":"","meta":{"footnotes":""},"class_list":["post-1116","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/pages\/1116","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/comments?post=1116"}],"version-history":[{"count":9,"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/pages\/1116\/revisions"}],"predecessor-version":[{"id":1145,"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/pages\/1116\/revisions\/1145"}],"up":[{"embeddable":true,"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/pages\/1598"}],"wp:attachment":[{"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/media?parent=1116"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}