{"id":1120,"date":"2011-11-14T17:03:02","date_gmt":"2011-11-14T08:03:02","guid":{"rendered":"http:\/\/www.qcri.or.jp\/lab\/?page_id=1120"},"modified":"2011-11-18T13:52:14","modified_gmt":"2011-11-18T04:52:14","slug":"re_structure","status":"publish","type":"page","link":"https:\/\/qcri.or.jp\/lab\/ja\/research_ja\/re_structure","title":{"rendered":"\u591a\u91cd\u7d50\u5408\u306e\u96fb\u5b50\u69cb\u9020\u3068\u53cd\u5fdc\u6027"},"content":{"rendered":"<div id=\"paragraph\"><img loading=\"lazy\" decoding=\"async\" class=\"alignright\" src=\"https:\/\/qcri.or.jp\/lab\/imgs\/Nb-C1.png\" alt=\"Nb-C multibonds\" width=\"402\" height=\"244\" \/><\/div>\n<div>\u3000\u91d1\u5c5e\u3068\u70ad\u7d20\u306e\u591a\u91cd\u7d50\u5408\u306f\u3001\u6709\u6a5f\u91d1\u5c5e\u5316\u5b66\u306b\u304a\u3051\u308b\u4ee3\u8868\u7684\u306a\u7d50\u5408\u69d8\u5f0f\u3067\u3059\u3002 \u5e7e\u3064\u304b\u306e\u6709\u6a5f\u91d1\u5c5e\u5316\u5b66\u53cd\u5fdc\u3067\u3001\u305d\u306e\u7d50\u5408\u751f\u6210\u30fb\u89e3\u96e2\u306f\u91cd\u8981\u306a\u30b9\u30c6\u30c3\u30d7\u3067\u3059\u3002 \u91d1\u5c5e\u3068\u70ad\u7d20\u306e\u591a\u91cd\u7d50\u5408\u306b\u306f\u3001Fisher\u578b\u3068Schrock\u578b\u306e2\u3064\u304c\u3042\u308b\u3053\u3068\u304c\u77e5\u3089\u308c\u3066\u304a\u308a\u3001 \u305d\u306e\u53cd\u5fdc\u6027\u306b\u9055\u3044\u304c\u898b\u3089\u308c\u307e\u3059\u3002<\/div>\n<div>&nbsp;<\/div>\n<div>\u30001980\u5e74\u4ee3\u521d\u3081\u3001\u4e2d\u8fbb\u3089\u306f\u3001\u91d1\u5c5e\u2015\u70ad\u7d20\u591a\u91cd\u7d50\u5408\u306e\u5206\u5b50\u8ecc\u9053\u8a08\u7b97\u3092\u884c\u3044\u3001 \u53cd\u5fdc\u6027\u306e\u9055\u3044\u3092\u7406\u8ad6\u304b\u3089\u8aac\u660e\u3057\u307e\u3057\u305f\u3002 \u3053\u308c\u3089\u6709\u6a5f\u91d1\u5c5e\u306e\u53cd\u5fdc\u6027\u306f\u3001\u96fb\u8377\u30b3\u30f3\u30c8\u30ed\u30fc\u30eb\u306e\u53cd\u5fdc\u6a5f\u69cb\u3067\u306f\u8aac\u660e\u3067\u304d\u305a\u3001 \u30d5\u30ed\u30f3\u30c6\u30a3\u30a2\u8ecc\u9053\u7406\u8ad6\u306b\u3088\u308a\u3001\u7d71\u4e00\u7684\u306b\u7406\u89e3\u3067\u304d\u308b\u3053\u3068\u3092\u793a\u3057\u307e\u3057\u305f\u3002 \u3055\u3089\u306b\u3001\u91d1\u5c5e\u2015\u70ad\u7d20\u7d50\u5408\u56de\u308a\u306e\u56de\u8ee2\u306f\u3001\u307b\u3068\u3093\u3069\u81ea\u7531\u56de\u8ee2\u3067\u3042\u308a\u3001 \u70ad\u7d20\u2015\u70ad\u7d20\u591a\u91cd\u7d50\u5408\u3068\u5927\u304d\u304f\u7570\u306a\u308b\u3053\u3068\u3092\u793a\u3057\u307e\u3057\u305f\u3002 \u307e\u305f\u3001\u91d1\u5c5e\u2015\u30b1\u30a4\u7d20\u591a\u91cd\u7d50\u5408\u306b\u3064\u3044\u3066\u3082\u691c\u8a0e\u3057\u3001\u305d\u306e\u53ef\u80fd\u6027\u3092\u793a\u3057\u307e\u3057\u305f\u3002<\/div>\n<div>&nbsp;<\/div>\n<hr \/>\n<div id=\"reference\"><strong>References<\/strong><\/div>\n<ul>\n<li>Ab Initio Electronic Structures and Reactivities of Metal Carbene Complexes:  Fischer-Type Compounds, (CO)<sub>5<\/sub>Cr=CH(OH) and (CO)<sub>4<\/sub>Fe=CH(OH),  H. Nakatsuji, J. Ushio, S. Han, and T. Yonezawa, J. Am. Chem. Soc., 105, 426 (1983).<\/li>\n<li>Electronic Structures and Reactivities of Metal-Carbon Multiple Bonds;  Schrock-Type Metal-Carbene Complex and Metal-Carbyne Complex,  J. Ushio, H. Nakatsuji, and T. Yonezawa, J. Am. Chem. Soc., 106, 5892 (1984).<\/li>\n<li>Does a Silylene-Metal Complex Exist?,  H. Nakatsuji, J. Ushio, and T. Yonezawa, J. Organometal. Chem., 258, C1-C4 (1983).<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"<p>\u3000\u91d1\u5c5e\u3068\u70ad\u7d20\u306e\u591a\u91cd\u7d50\u5408\u306f\u3001\u6709\u6a5f\u91d1\u5c5e\u5316\u5b66\u306b\u304a\u3051\u308b\u4ee3\u8868\u7684\u306a\u7d50\u5408\u69d8\u5f0f\u3067\u3059\u3002 \u5e7e\u3064\u304b\u306e\u6709 &hellip; <a href=\"https:\/\/qcri.or.jp\/lab\/ja\/research_ja\/re_structure\">\u7d9a\u304d\u3092\u8aad\u3080 <span class=\"meta-nav\">&rarr;<\/span><\/a><\/p>\n","protected":false},"author":2,"featured_media":0,"parent":1598,"menu_order":0,"comment_status":"closed","ping_status":"open","template":"","meta":{"footnotes":""},"class_list":["post-1120","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/pages\/1120","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/comments?post=1120"}],"version-history":[{"count":6,"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/pages\/1120\/revisions"}],"predecessor-version":[{"id":1672,"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/pages\/1120\/revisions\/1672"}],"up":[{"embeddable":true,"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/pages\/1598"}],"wp:attachment":[{"href":"https:\/\/qcri.or.jp\/lab\/wp-json\/wp\/v2\/media?parent=1120"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}